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Ken Tanaka Rhodium Catalysis in Organic Synthesis. Methods and Reactions


An essential reference to the highly effective reactions applied to modern organic synthesis Rhodium complexes are one of the most important transition metals for organic synthesis due to their ability to catalyze a variety of useful transformations. Rhodium Catalysis in Organic Synthesis: Methods and Reactions explores the most recent progress and new developments particularly in the field of catalytic cyclization reactions using rhodium(I) complexes and catalytic carbon-hydrogen bond activation reactions using rhodium(II) and rhodium(III) complexes. Edited by a noted expert in the field with contributions from a panel of leading international scientists, Rhodium Catalysis in Organic Synthesis: Methods and Reactions presents the essential information in one comprehensive volume. Designed to be an accessible resource, the book is arranged by different reaction types. All the chapters provide insight into each transformation and include information on the history, selectivity, scope, mechanism, and application. In addition, the chapters offer a summary and outlook of each transformation. This important resource: Offers a comprehensive review of how rhodium complexes catalyze a variety of highly useful reactions for organic synthesis (e.g. coupling reactions, CH-bond functionalization, hydroformylation, cyclization reactions and others) Includes information on the most recent developments that contain a range of new, efficient, elegant, reliable and useful reactions Presents a volume edited by one of the international leading scientists working in the field today Contains the information that can be applied by researchers in academia and also professionals in pharmaceutical, agrochemical and fine chemical companies Written for academics and synthetic chemists working with organometallics, Rhodium Catalysis in Organic Synthesis: Methods and Reactions contains the most recent information available on the developments and applications in the field of catalytic cyclization reactions using rhodium complexes.

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Chao-Jun Li Silver Catalysis in Organic Synthesis, 2 Volume Set


Covers all the aspects of the recent achievements in silver catalyzed reactions Silver catalysis has emerged as a powerful tool in the field of organic synthesis. This comprehensive book systematically explores the unique performance of silver catalysis, introducing all the recent progress of silver catalysis in organic synthesis. It clearly emphasizes the unique features of silver catalysis and provides the reaction mechanism involved. This two-volume book also provides vivid schematics and tables throughout to enhance the accessibility to the relevant theory and mechanisms. Silver Catalysis in Organic Synthesis begins with an introduction to Silver Chemistry before moving on to chapters covering: Silver-Catalyzed Cycloaddition Reactions; Silver-Catalyzed Cyclizations; Silver-Mediated Radical Reactions; Silver-Mediated Fluorination, Perfluoroalkylation and Trifluoromethylthiolation Reactions; Coupling Reactions and C-H Functionalization; Silver-Catalyzed CO2 Incorporation; Silver-Catalyzed Carbene, Nitrene, and Silylene Transfer Reactions; Asymmetric Silver-Catalyzed Reactions; Silver-Catalyzed Reduction and Oxidation of Aldehydes and Their Derivatives; Silver Complexes in Organic Transformations; and Silver Nanoparticles in Organic Transformations. -Covers recently developed organic reactions catalyzed by silver, along with their reaction mechanism -Introduces many new reactions and mechanisms related to silver catalysis -Offers professionals and newcomers in the related fields a survey of new advances in silver catalysis in organic synthesis Silver Catalysis in Organic Synthesis will appeal to a wide readership including chemists, biochemists, pharmaceutical scientists, biomedical researchers, agriculture scientists, and graduate students in the related fields.

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Jian Zhou Multicatalyst System in Asymmetric Catalysis


This book introduces multi-catalyst systems by describing their mechanism and advantages in asymmetric catalysis. • Helps organic chemists perform more efficient catalysis with step-by-step methods • Overviews new concepts and progress for greener and economic catalytic reactions • Covers topics of interest in asymmetric catalysis including bifunctional catalysis, cooperative catalysis, multimetallic catalysis, and novel tandem reactions • Has applications for pharmaceuticals, agrochemicals, materials, and flavour and fragrance

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Группа авторов Science of Synthesis: Dual Catalysis in Organic Synthesis 2

Jiro Tsuji Modern Rhodium-Catalyzed Organic Reactions


Rhodium has proven to be an extremely useful metal due to its ability to catalyze an array of synthetic transformations, with quite often-unique selectivity. Hydrogenation, C-H activation, allylic substitution, and numerous other reactions are catalyzed by this metal, which presumably accounts for the dramatic increase in the number of articles that have recently emerged on the topic. P. Andrew Evans, the editor of this much-needed book, has assembled an internationally renowned team to present the first comprehensive coverage of this important area. The book features contributions from leaders in the field of rhodium-catalyzed reactions, and thereby provides a detailed account of the most current developments, including: Rhodium-Catalyzed Asymmetric Hydrogenation (Zhang) Rhodium-Catalyzed Hydroborations and Related Reactions (Brown) Rhodium-Catalyzed Asymmetric Addition of Organometallic Reagents to Electron Deficient Olefins (Hayashi) Recent Advances in Rhodium(I)-Catalyzed Asymmetric Olefin Isomerization and Hydroacylation Reactions (Fu) Stereoselective Rhodium(I)-Catalyzed Hydroformylation and Silylformylation Reactions and Their Application to Organic Synthesis (Leighton) Carbon-Carbon Bond-Forming Reactions Starting from Rh-H or Rh-Si Species (Matsuda) Rhodium(I)-Catalyzed Cycloisomerization and Cyclotrimerization Reactions (Ojima) The Rhodium(I)-Catalyzed Alder-ene Reaction (Brummond) Rhodium-Catalyzed Nucleophilic Ring Cleaving Reactions of Allylic Ethers and Amines (Fagnou) Rhodium(I)-Catalyzed Allylic Substitution Reactions and their Applications to Target Directed Synthesis (Evans) Rhodium(I)-Catalyzed [2+2+1] and [4+1] Carbocyclization Reactions (Jeong) Rhodium(I)-Catalyzed [4+2] and [4+2+2] Carbocyclizations (Robinson) Rhodium(I)-Catalyzed [5+2], [6+2], and [5+2+1] Cycloadditions: New Reactions for Organic Synthesis (Wender) Rhodium(II)-Stabilized Carbenoids Containing both Donor and Acceptor Substituents (Davies) Chiral Dirhodium(II)Carboxamidates for Asymmetric Cyclopropanation and Carbon-Hydrogen Insertion Reactions (Doyle) Cyclopentane Construction by Rhodium(II)-Mediated Intramolecular C-H Insertion (Taber) Rhodium(II)-Catalyzed Oxidative Amination (DuBois) Rearrangement Processes of Oxonium and Ammonium Ylides Formed by Rhodium(II)-Catalyzed Carbene-Transfer (West) Rhodium(II)-Catalyzed 1,3-Dipolar Cycloaddition Reactions (Austin) «Modern Rhodium-Catalyzed Organic Reactions» is an essential reference text for researchers at all levels in the general area of organic chemistry. This book provides an invaluable overview of the most significant developments in this important area of research, and will no doubt be an essential text for researchers at academic institutions and professionals at pharmaceutical/agrochemical companies.

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Группа авторов Science of Synthesis: Dual Catalysis in Organic Synthesis 1

Ken Tanaka Transition-Metal-Mediated Aromatic Ring Construction


State-of-the-science methods, synthetic routes, and strategies to construct aromatic rings The development of new reactions for the synthesis of aromatic compounds is a highly active research area in organic synthesis, providing new functional organic materials, functional reagents, and biologically active compounds. Recently, significant advances in transition-metal-mediated reactions have enabled the efficient and practical construction of new aromatic rings with useful properties and applications. This book draws together and reviews all the latest discoveries and methods in transition-metal-mediated reactions, offering readers promising new routes to design and construct complex aromatic compounds. Integrating metal catalysis with aromatic compound synthesis, Transition-Metal-Mediated Aromatic Ring Construction offers a practical guide to the methods, synthetic routes, and strategies for constructing aromatic compounds. The book's five parts examine: [2+2+2], [2+2+1], and related cycloaddition reactions [4+2], [3+2], and related cycloaddition reactions Electrocyclization reactions Coupling and addition reactions Other important transformations, including methathesis reactions and skeletal rearrangement reactions Edited by Ken Tanaka, an internationally recognized expert in the field of transition-metal catalysis, the book features authors who are leading pioneers and researchers in synthetic reactions. Their contributions reflect a thorough review and analysis of the literature as well as their own firsthand laboratory experience developing new aromatic compounds. All chapters end with a summary and outlook, setting forth new avenues of research and forecasting new discoveries. There are also references at the end of each chapter, guiding readers to important original research reports and reviews. In summary, Transition-Metal-Mediated Aromatic Ring Construction offers synthetic chemists a promising new avenue for the development of important new aromatic compounds with a broad range of applications.

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Satoshi Horikoshi Microwaves in Catalysis


A comprehensive overview covering the principles and preparation of catalysts, as well as reactor technology and applications in the field of organic synthesis, energy production, and environmental catalysis. Edited and authored by renowned and experienced scientists, this reference focuses on successful reaction procedures for applications in industry. Topics include catalyst preparation, the treatment of waste water and air, biomass and waste valorisation, hydrogen production, oil refining as well as organic synthesis in the presence of heterogeneous and homogeneous catalysts and continuous-flow reactions. With its practical relevance and successful methodologies, this is a valuable guide for chemists at universities working in the field of catalysis, organic synthesis, pharmaceutical or green chemistry, as well as researchers and engineers in the chemical industry.

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Rhodium Catalysis in Organic Synthesis: Methods and ...

Rhodium Catalysis in Organic Synthesis: Methods and Reactions | Ken Tanaka | ISBN: 9783527343645 | Kostenloser Versand für alle Bücher mit Versand und Verkauf duch Amazon.

Rhodium Catalysis in Organic Synthesis | Wiley Online Books

Ken Tanaka is a Professor of Applied Chemistry in the Department of Chemical Science and Engineering at the Tokyo Institute of Technology. Since the start of his academic career in 2003, he has published over 190 scientific papers and one book. His research focuses on organometallic chemistry directed toward organic synthesis.

Rhodium Catalysis in Organic Synthesis: Methods and ...

Rhodium Catalysis in Organic Synthesis: Methods and Reactions (English Edition) eBook: Ken Tanaka: Amazon.de: Kindle-Shop

Rhodium(I)‐Catalyzed [2+2+2] and [4+2] Cycloadditions ...

Shunsuke Suzuki, Yu Shibata, Ken Tanaka, Rhodium‐Catalyzed Asymmetric [2+2+2] Cycloaddition of 1,6‐Enynes with Racemic Secondary Allylic Alcohols through Kinetic Resolution, Chemistry – A European Journal, 10.1002/chem.202000010, 26, 17, (3698-3702), (2020). Wiley Online Library. Yukimasa Aida, Juntaro Nogami, Haruki Sugiyama, Hidehiro Uekusa, Ken Tanaka, Enantioselective Synthesis of ...

Rhodium Catalysis in Organic Synthesis von Ken Tanaka ...

Rhodium Catalysis in Organic Synthesis von Ken Tanaka (ISBN 978-3-527-81190-8) - lehmanns.de

Cationic Rhodium(I)/Modified‐BINAP Catalyzed [2+2+2 ...

Ken Tanaka, Rhodium-Catalyzed [2+2+2] Cycloaddition for the Synthesis of Substituted Pyridines, Pyridones, and Thiopyranimines, HETEROCYCLES, 10.3987/REV-12-729, 85, 5, (1017), (2012). Crossref. Ryan M. Stolley, Hung A. Duong, David R. Thomas, Janis Louie, The Discovery of [Ni(NHC)RCN] 2 Species and Their Role as Cycloaddition Catalysts for the Formation of Pyridines , Journal of the American ...

Rhodium Catalysis in Organic Synthesis : Methods and ...

Get this from a library! Rhodium Catalysis in Organic Synthesis : Methods and Reactions.. [Ken Tanaka] -- An essential reference to the highly effective reactions applied to modern organic synthesis Rhodium complexes are one of the most important transition metals for organic synthesis due to their ...

Rhodium‐Catalyzed ortho ‐Bromination of O‐Phenyl ...

Jin Tanaka, Yuki Nagashima, Ken Tanaka, Rhodium(III)-Catalyzed Oxidative ortho -Olefination of Phenyl Carbamates with Alkenes: Elucidation of Acceleration Mechanisms by Using an Unsubstituted Cyclopentadienyl Ligand , Organic Letters, 10.1021/acs.orglett.0c02499, (2020).

Rhodium-Catalyzed Highly Enantioselective Direct ...

Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes Yu Shibata and Ken Tanaka* *Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan, Email: tanaka-k cc.tuat.ac.jp

Cationic Rhodium(I)/Modified-BINAP Catalyzed [2+2+2 ...

Cationic Rhodium(I)/Modified-BINAP Catalyzed [2+2+2] Cycloaddition of Alkynes with Nitriles Ken Tanaka *, Nanami Suzuki, Goushi Nishida *Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan, Email: tanaka-k cc.tuat.ac.jp. K. Tanaka, N. Suzuki, G. Nishida, Eur. J. Org. Chem., 2006, 3917-3922. DOI: 10.1002 ...

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Enantioselective Synthesis of Planar Chiral Zigzag-Type ...

Planar chiral zigzag-type [8]- and [12]cyclophenylene (CP) belts have been synthesized in good yields with high ee values of 98% and 83%, respectively, by the rhodium-catalyzed enantioselective intramolecular sequential cyclotrimerizations of the corresponding cyclic polyynes. The observed high enan …

Электронная книга: Ken Tanaka. Rhodium Catalysis in ...

An essential reference to the highly effective reactions applied to modern organic synthesis Rhodium complexes are one of the most important transition metals for organic synthesis due to their ability to catalyze a variety of useful transformations. Rhodium Catalysis in Organic Synthesis: Methods and Reactions explores the most recent progress and new developments particularly in the field of ...

Rhodium Catalysis in Organic Synthesis – Ken Tanaka (2019 ...

Englisches Buch: Rhodium Catalysis in Organic Synthesis - von Ken Tanaka - (Wiley-VCH) - ISBN: 3527343644 - EAN: 9783527343645

Wiley-VCH - Rhodium Catalysis in Organic Synthesis

Ken Tanaka presents this field comprehensively in this reference. Jetzt kaufen. Preis: 189,00 € Preis inkl. MwSt, zzgl. Versand. In den Warenkorb. Weitere Versionen. Beschreibung; Inhalt; Autoreninfo; An essential reference to the highly effective reactions applied to modern organic synthesis Rhodium complexes are one of the most important transition metals for organic synthesis due to their ...

Rhodium catalysis in organic synthesis - methodsand ...

Rhodium catalysis in organic synthesis - methodsand reactions | TANAKA, KEN | download | B–OK. Download books for free. Find books

Highly Chemo- and Regioselective Intermolecular ...

Ken Tanaka,, Hiromi Sagae,, Kazuki Toyoda,, Keiichi Noguchi, and, Masao Hirano. Enantioselective Synthesis of Planar-Chiral Metacyclophanes through Rhodium-Catalyzed Alkyne Cyclotrimerization. Journal of the American Chemical Society 2007 , 129 (6) , 1522-1523.

Rhodium Catalysis in Organic Synthesis: Methods and ...

An essential reference to the highly effective reactions applied to modern organic synthesis Rhodium complexes are one of the most important transition metals for organic synthesis due to their ability to catalyze a variety of useful transformations. Rhodium Catalysis in Organic...

田中 健 | 研究者情報 | J-GLOBAL 科学技術総合リンクセンター

Ken Tanaka, Eri Okazaki, Yu Shibata. Cationic rhodium(I) complex-catalyzed sigma- and pi-bond activation cascade: Isomerization of allyl propargyl ethers to allenic aldehydes and dienals. PURE AND APPLIED CHEMISTRY. 2010. 82. 7. 1453-1460; K. Tanaka, E. Okazaki, Y. Shibata. Cationic Rhodium(I) Complex-Catalyzed σ- and π-Bond Activation ...

Synthesis of Belt- and Möbius-Shaped Cycloparaphenylenes ...

Juntaro Nogami, Yusuke Tanaka, Haruki Sugiyama, Hidehiro Uekusa, Atsuya Muranaka, Masanobu Uchiyama, Ken Tanaka. Enantioselective Synthesis of Planar Chiral Zigzag-Type Cyclophenylene Belts by Rhodium-Catalyzed Alkyne Cyclotrimerization. Journal of the American Chemical Society 2020, 142 (21) , 9834-9842.

Rhodium Catalysis in Organic Synthesis: Methods and ...

Ken Tanaka is a Professor of Applied Chemistry in the Department of Chemical Science and Engineering at the Tokyo Institute of Technology. Since the start of his academic career in 2003, he has published over 190 scientific papers and one book. His research focuses on organometallic chemistry directed toward organic synthesis.

Rhodium Catalysis in Organic Synthesis : Methods and ...

Rhodium Catalysis in Organic Synthesis : Methods and Reactions by Ken Tanaka (2019, Hardcover) Be the first to write a review. About this product. Current slide {CURRENT_SLIDE} of {TOTAL_SLIDES}- Top picked items. Brand new. $223.48. New (other) $222.90 ...

Wiley-VCH - Rhodium Catalysis in Organic Synthesis

Ken Tanaka presents this field comprehensively in this reference. Buy now. Price: 189,00 € Price incl. VAT, excl. Shipping. Add to Cart. Further versions. Description; Content; Author information; An essential reference to the highly effective reactions applied to modern organic synthesis Rhodium complexes are one of the most important transition metals for organic synthesis due to their ...

Rhodium Catalysis in Organic Synthesis: Ken Tanaka ...

Rhodium Catalysis in Organic Synthesis | An essential reference to the highly effective reactions applied to modern organic synthesis Rhodium complexes are one of the most important transition metals for organic synthesis due to their ability to catalyze a variety of useful transformations.

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An essential reference to the highly effective reactions applied to modern organic synthesis Rhodium complexes are one of the most important transition metals for organic synthesis due to their ability to catalyze a variety of useful transformations.

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Rhodium Catalysis in Organic Synthesis - ISBN ...

von: Ken Tanaka. 169,99 € Verlag: ... Rhodium Catalysis in Organic Synthesis explores the most recent progress and new developments in the field of catalytic cyclization reactions using rhodium(I) complexes and catalytic carbon-hydrogen bond activation reactions using rhodium(II) and rhodium(III) complexes. <br> <br> Edited by a noted expert in the field with contributions from a panel of ...

Ken Tanaka's research works | Tokyo Institute of ...

Ken Tanaka's 269 research works with 6,620 citations and 1,185 reads, including: Enantioselective Synthesis of Polycyclic Aromatic Hydrocarbon (PAH)‐Based Planar Chiral Bent Cyclophanes by ...

Ken Tanaka - Cochemist

Rhodium-Catalyzed [2+2+2] Cycloaddition of Diynes with Carbodiimides and Carbon Dioxide under Ambient Conditions . Co-reporter: Masahiro Ishii;Fumiya Mori;Dr. Ken Tanaka. Chemistry - A European Journal 2014 Volume 20( Issue 8) pp:2169-2174 . Publication Date(Web): DOI: 10.1002/chem.201304623. Abstract ...

‎Rhodium Catalysis in Organic Synthesis on Apple Books

‎An essential reference to the highly effective reactions applied to modern organic synthesis Rhodium complexes are one of the most important transition metals for organic synthesis due to their ability to catalyze a variety of useful transformations. Rhodium Catalysis in Organic Synthes…

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Rhodium-Catalyzed Synthesis, Crystal Structures, and ...

Rhodium-Catalyzed Synthesis, Crystal Structures, and Photophysical Properties of [6]Cycloparaphenylene Tetracarboxylates. Norihiko Hayase, Haruki Sugiyama, Hidehiro Uekusa, Yu Shibata, Ken Tanaka. Research output: Contribution to journal › Article. 1 Citation (Scopus) Abstract. The synthesis of C 2-symmetrical [6]cycloparaphenylene (CPP) tetracarboxylates has been achieved via ...

Rhodium Catalysis in Organic Synthesis :: Ken Tanaka books ...

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Transition-Metal-Mediated Aromatic Ring Construction ...

State-of-the-science methods, synthetic routes, andstrategies to construct aromatic rings The development of new reactions for the synthesis of aromaticcompounds is a highly active research area in organic synthesis,providing new functional organic materials, functional reagents,and biologically active compounds.

Synthesis of Pyridylphosphonates by Rhodium‐Catalyzed [2+2 ...

The convenient and atom-economical synthesis of substituted bicyclic pyridylphosphonates has been achieved by the cationic rhodium(I)/H8-binap-complex-catalyzed [2+2+2] cycloaddition of 1,6- and 1,7-diynes with diethyl phosphorocyanidate. These reactions may proceed via an azarhodacyclopentadiene intermediate in addition to the rhodacyclopentadiene intermediate.

Wiley: Transition-Metal-Mediated Aromatic Ring ...

9.4 Rhodium-Catalyzed Enantioselective [2+2+2] Cycloaddition, 263. 9.5 Enantioselective Synthesis of Axially Chiral Anilides and Bezamides, 275. 9.6 Summary and Outlook, 278 . References, 278. 10 Synthesis of Helically Chiral Aromatic Compounds via [2+2+2] Cycloaddition 281 Ken Tanaka. 10.1 Introduction, 281. 10.2 Nonasymmetric Synthesis, 281. 10.3 Diastereoselective Synthesis, 287. 10.4 ...

Rhodium Catalysis in Organic Synthesis - ISBN ...

Rhodium Catalysis in Organic Synthesis - ISBN: 9783527811878 - (ebook) - von Ken Tanaka, Verlag: Wiley-VCH

Citation - PubAg

Sawada, Yayoi, Seiichi Furumi, Atsuro Takai, Masayuki Takeuchi, Keiichi Noguchi, and Ken Tanaka. "Rhodium-Catalyzed Enantioselective Synthesis, Crystal Structures, and Photophysical Properties of Helically Chiral 1,1′-Bitriphenylenes" Journal of the American Chemical Society 134, no. 9 (2012): 4080-4083. doi: 10.1021/ja300278e

Rhodium - Lexikon der Physik

Rhodium, Rh, ein Edelmetall, Element der Nebengruppe VIII (5. Periode) des Periodensystems, der Platinmetallgruppe, bzw. der Gruppe Nr. 9 des Langperiodensystems, Ordnungszahl 45. Rhodium besitzt die Elektronenkonfiguration [Kr]4d 8 5s 1 und besteht zu 100 % aus dem Isotop (siehe Tab. 1). Technische ...

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Rhodium Catalysis in Organic Synthesis von: Ken Tanaka. Verlag: Wiley-VCH Preis: 169,99 € Format: ...

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Ken Tanaka - consulte a biografia e bibliografia do autor de Rhodium Catalysis For Organic Synthesis e Transition-Metal-Mediated Aromatic Ring Construction

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Ken Tanaka, Actor: Bokyo. Ken Tanaka was born on March 6, 1951. He is an actor, known for Bokyo (1993), Godzilla 1985 (1985) and The Gate of Youth (1975). He was previously married to Yûko Kotegawa.

Synthesis of CF3-Containing Isoindolinone Derivatives ...

Risa Yoshimoto , 1 Hideaki Morisaka , 1 Yoshinosuke Usuki , 1 Yu Shibata , 2 Ken Tanaka , 2 and Tetsuya Satoh * 1 1 Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585

Yu Shibata's research works | Tokyo Institute of ...

Ken Tanaka Dibenzo[7]helicenes were synthesized with up to 99% ee via the rhodium(I)/binap complex-catalyzed enantioselective intramolecular [2+2+2] cycloaddition of 2-phenylnaphthalene-linked ...

Shibata Yu | Researcher Information | J-GLOBAL

Hiroshi Kanno, Kyosuke Nakamura, Keiichi Noguchi, Yu Shibata, Ken Tanaka. Rhodium-Catalyzed Cycloisomerization of 2-Silylethynyl Phenols and Anilines via 1,2-Silicon Migration. ORGANIC LETTERS. 2016. 18. 7. 1654-1657; Soichi Yoshizaki, Yu Nakamura, Koji Masutomi, Tomoka Yoshida, Keiichi Noguchi, Yu Shibata, Ken Tanaka. Rhodium-Catalyzed ...

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Enantioselective Synthesis of Planar Chiral Zigzag-Type ...

Juntaro Nogami, Yusuke Tanaka, Haruki Sugiyama, Hidehiro Uekusa, Atsuya Muranaka, Masanobu Uchiyama, Ken Tanaka. 文学部 ; 研究成果: Article. 概要; フィンガープリント; 抜粋. Planar chiral zigzag-type [8]- and [12]cyclophenylene (CP) belts have been synthesized in good yields with high ee values of 98% and 83%, respectively, by the rhodium-catalyzed enantioselective ...

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Liu Yan Bridging Heterogeneous and Homogeneous Catalysis. Concepts, Strategies, and Applications


This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts.

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Pher Andersson G. Innovative Catalysis in Organic Synthesis. Oxidation, Hydrogenation, and C-X Bond Forming Reactions


C-H, C-O, C-C, and C-Heteroatom bond forming processes by using metal-ligand approaches for the synthesis of organic compounds of biological, pharmacological and organic nanotechnological utility are the key areas addressed in this book. Authored by a European team of leaders in the field, it brings together innovative approaches for a variety of catalysis reactions and processes frequently applied in organic synthesis into a handy reference work. It covers all major types of catalysis, including homogeneous, heterogeneous, and organocatalysis, as well as mechanistic and computational studies. Special attention is paid to the improvements in efficiency and sustainability of important catalytic processes, such as selective oxidations, hydrogenation, and cross-coupling reactions, and to their utilization in industry. The result is a valuable resource for advanced researchers in both academia and industry, as well as graduate students in organic chemistry aiming for chemo-, regio- or stereoselective synthesis of organic compounds by using novel catalytic systems.

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Группа авторов Lewis Base Catalysis in Organic Synthesis


This three-volume set represents the first comprehensive coverage of the rapidly expanding field of Lewis base catalysis that has attracted enormous attention in recent years. Lewis base catalysis is a conceptually novel paradigm that encompasses an extremely wide variety of preparatively useful transformations and is particularly effective for enantioselectively constructing new stereogenic centers. As electron-pair donors, Lewis bases can influence the rate and stereochemical course of myriad synthetic organic reactions. The book presents the conceptual/mechanistic principles that underlie Lewis base catalysis, and then builds upon that foundation with a thorough presentation of many different reaction types. And last but not least, the editors, Prof. Edwin Vedejs and Prof. Scott E. Denmark, are without doubt the leaders in this emerging field and have compiled high quality contributions from an impressive collection of international experts.

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David Farrusseng Metal-Organic Frameworks. Applications from Catalysis to Gas Storage


An international and interdisciplinary team of leading experts from both academia and industry report on the wide range of hot applications for MOFs, discussing both the advantages and limits of the material. The resulting overview covers everything from catalysis, H2 and CH4 storage and gas purification to drug delivery and sensors. From the Contents: – Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future – Design of Functional Metal-Organic Frameworks by Post-Synthetic Modification – Thermodynamic Methods for Prediction of Gas Separation in Flexible Frameworks – Separation and purification of gases by MOFs – Opportunities for MOFs in CO2 capture from flue gases, natural gas and syngas by adsorption – Manufacture of MOF thin films on structured supports for separation and catalysis – Research status of Metal-Organic Frameworks for on-board cryo-adsorptive hydrogen storage applications – Separation of xylene isomers – Metal-Organic Frameworks as Catalysts for Organic Reactions – Biomedical applications of Metal Organic Frameworks – Metal Organic Frameworks for Biomedical Imaging – Luminescent Metal-Organic Frameworks – Deposition of thin films for sensor applications – Industrial MOF Synthesis – MOF shaping and immobilisation A must-have for every scientist in the field.

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David Farrusseng Metal-Organic Frameworks. Applications from Catalysis to Gas Storage


An international and interdisciplinary team of leading experts from both academia and industry report on the wide range of hot applications for MOFs, discussing both the advantages and limits of the material. The resulting overview covers everything from catalysis, H2 and CH4 storage and gas purification to drug delivery and sensors. From the Contents: – Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future – Design of Functional Metal-Organic Frameworks by Post-Synthetic Modification – Thermodynamic Methods for Prediction of Gas Separation in Flexible Frameworks – Separation and purification of gases by MOFs – Opportunities for MOFs in CO2 capture from flue gases, natural gas and syngas by adsorption – Manufacture of MOF thin films on structured supports for separation and catalysis – Research status of Metal-Organic Frameworks for on-board cryo-adsorptive hydrogen storage applications – Separation of xylene isomers – Metal-Organic Frameworks as Catalysts for Organic Reactions – Biomedical applications of Metal Organic Frameworks – Metal Organic Frameworks for Biomedical Imaging – Luminescent Metal-Organic Frameworks – Deposition of thin films for sensor applications – Industrial MOF Synthesis – MOF shaping and immobilisation A must-have for every scientist in the field.

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Jan-E. Bäckvall Artificial Metalloenzymes and MetalloDNAzymes in Catalysis


An important reference for researchers in the field of metal-enzyme hybrid catalysis Artificial Metalloenzymes and MetalloDNAzymes in Catalysis offers a comprehensive review of the most current strategies, developed over recent decades, for the design, synthesis, and optimization of these hybrid catalysts as well as material about their application. The contributors—noted experts in the field—present information on the preparation, characterization, and optimization of artificial metalloenzymes in a timely and authoritative manner. The authors present a thorough examination of this interesting new platform for catalysis that combines the excellent selective recognition/binding properties of enzymes with transition metal catalysts. The text includes information on the various applications of metal-enzyme hybrid catalysts for novel reactions, offers insights into the latest advances in the field, and contains an informative perspective on the future: Explores the development of artificial metalloenzymes, the modern and strongly evolving research field on the verge of industrial application Contains a comprehensive reference to the research area of metal-enzyme hybrid catalysis that has experienced tremendous growth in recent years Includes contributions from leading researchers in the field Shows how this new catalysis combines the selective recognition/binding properties of enzymes with transition metal catalysts Written for catalytic chemists, bioinorganic chemists, biochemists, and organic chemists, Artificial Metalloenzymes and MetalloDNAzymes in Catalysis offers a unique reference to the fundamentals, concepts, applications, and the most recent developments for more efficient and sustainable synthesis.

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